Everything about TPPTS

🧭 Start here: a 6-step reading path

1. Read the overview: TPPTSA 5-minute orientation
2. Skim a recent paper: The influence of triphenylphosphine trisulfonate (TPPTS) ligands on the catalytic activity of the supported ionic liquid-phase catalysts for the hydroformylation of ethyleneInfluential work since 2022
3. Read the landmark paper: Introducing TPPTS and related ligands for industrial biphasic processesCited 340 times
4. Go sideways: HydroformylationA closely related topic
5. Go sideways: Metal-phosphine complexA closely related topic

🏆 Landmark papers (most cited)

• Introducing TPPTS and related ligands for industrial biphasic processes

  Boy Cornils, Emile G. Kuntz · 1995 · Journal of Organometallic Chemistry · 340 citations

• New synthetic applications of water-soluble acetate Pd/TPPTS catalyst generated in Situ. evidence for a true Pd(0) species intermediate

  Christian Amatore, Errol Blart, Jean Pierre Genet · 1995 · The Journal of Organic Chemistry · 195 citations

• Beyond TPPTS: New Approaches to the Development of Efficient Palladium‐Catalyzed Aqueous‐Phase Cross‐Coupling Reactions

  Kevin H. Shaughnessy · 2006 · European Journal of Organic Chemistry · 154 citations

• Suzuki cross-coupling of arylboronic acids mediated by a hydrosoluble Pd(0)/TPPTS catalyst

  Christophe Dupuis, Kouacou Adiey, Lise Charruault · 2001 · Tetrahedron Letters · 125 citations

• Experimental and kinetic modeling studies on the biphasic hydrogenation of levulinic acid to γ-valerolactone using a homogeneous water-soluble Ru–(TPPTS) catalyst

  M. Chalid, A.A. Broekhuis, H.J. Heeres · 2011 · Journal of Molecular Catalysis A: Chemical · 117 citations

• Wasserlösliche Metallkomplexe und Katalysatoren III. Neue wasserlösliche Metallkomplexe des sulfonierten Triphenylphosphans (TPPTS): Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Ag, Au

  Wolfgang A. Herrmann, Jürgen Kellner, Herbert Riepl · 1990 · Journal of Organometallic Chemistry · 103 citations

• Wasserlösliche Metallkomplexe und Katalysatoren II. Verfahren zur Reindarstellung von Tris(natrium-m-sulfonatophenyl)phosphan (TPPTS) und katalyserelevanter Rhodium-Komplexe

  Wolfgang A. Herrmann, Jürgen A. Kulpe, Werner Konkol · 1990 · Journal of Organometallic Chemistry · 99 citations

• Water‐Soluble Metal Complexes of the Sulfonated Triphenylphosphane TPPTS: Preparation of the Pure Compounds and their Use in Catalysis

  Wolfgang A. Herrmann, Jürgen A. Kulpe, Jürgen Kellner · 1990 · Angewandte Chemie International Edition in English · 87 citations

🆕 Influential since 2022

• The influence of triphenylphosphine trisulfonate (TPPTS) ligands on the catalytic activity of the supported ionic liquid-phase catalysts for the hydroformylation of ethylene

  Van Chuc Nguyen, Van Hung Do, Duc Duc Truong · 2023 · Research on Chemical Intermediates · 4 citations

• Investigation on reaction rate and kinetic modeling of heterogeneous hydroformylation of vinyl acetate over RhCl(TPPTS)3 encapsulated HMS catalyst

  N. Sudheesh, Ram S. Shukla · 2026 · Chemical Papers · 0 citations

• Correction to: The influence of triphenylphosphine trisulfonate (TPPTS) ligands on the catalytic activity of the supported ionic liquid-phase catalysts for the hydroformylation of ethylene

  Van Chuc Nguyen, Van Hung Do, Duc Duc Truong · 2023 · Research on Chemical Intermediates · 0 citations

• Hydrosoluble Pd(MesSO 3 )(TPPTS) catalyst for highly active and selective telomerization of 1,3-butadiene with methanol

  Muhammad Sajjad, Sivadasan Dharani, Karuppathevan Ramki · 2026 · Reaction Chemistry & Engineering · 0 citations

• Construction of a porous-ionic-polymer encapsulated Rh-TPPTS catalyst for regioselective hydroformylation

  Sen Feng, Cunyao Li, Guifa Long · 2026 · Chemical Engineering Journal · 0 citations

📚 Books worth reading

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🔗 Related topics

• Hydroformylation In organic chemistry, hydroformylation, also known as oxo synthesis or oxo process, is an industrial process for the production of aldehydes (R−CH=O) from…
• Metal-phosphine complex A metal-phosphine complex is a coordination complex containing one or more phosphine ligands. Almost always, the phosphine is an organophosphine of the…
• Triphenylphosphine Triphenylphosphine (IUPAC name: triphenylphosphane) is a common organophosphorus compound with the formula P(C6H5)3 and often abbreviated to PPh3 or Ph3P…
• Organorhodium chemistry Organorhodium chemistry is the chemistry of organometallic compounds containing a rhodium-carbon chemical bond, and the study of rhodium and rhodium compounds…
• Tris(4-methoxyphenyl)phosphine Tris(4-methoxyphenyl)phosphine is the organophosphorus compound with the formula (CH3OC6H4)3P. Several isomers of this formula are known, but the symmetrical…
• Tris(triphenylphosphine)rhodium carbonyl hydride Carbonyl hydrido tris(triphenylphosphine)rhodium(I) [Carbonyl(hydrido)tris(triphenylphosphane)rhodium(I)] is an organorhodium compound with the formula…
• Homogeneous catalysis In chemistry, homogeneous catalysis is catalysis where the catalyst is in same phase as reactants, principally by a soluble catalyst in a solution. In…
• Rhodium(III) chloride Rhodium(III) chloride refers to inorganic compounds with the formula RhCl3(H2O)n, where n varies from 0 to 3. These are diamagnetic red-brown solids. The…